Novel Pt and Pd Based Core-Shell Catalysts with Critical New Issues of Heat Treatment, Stability and Durability for Proton Exchange Membrane Fuel Cells and Direct Methanol Fuel Cells
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چکیده
منابع مشابه
Synthesis of Sulfonated Polystyrene/acrylate–ionic Liquid (Si-SPS/A–IL) Hybrid Membranes for Methanol Fuel Cells
In this paper, the silicon-containing sulfonated polystyrene/acrylate–ionic liquid (Si-SPS/A–IL)hybrid membranes was prepared to obtain the proton exchange membrane (PEM) materials withhigh methanol barrier and good selectivity. The Si-SPS/A–IL hybrid membranes characterized asthe function of IL to evaluate their potential as PEMs in direct methanol fuel cells (DMFCs).Fourdifferent Hybrid mater...
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A novel proton exchange membrane has been prepared using sulfonated poly(styrene-divinylbenzene) resin(SPSDR)–polyethylene(PE). The membrane is characterized by FT-IR, SEM and TGA/DSC. Water uptake, oxidative resistance, ionic conductivity and methanol permeability are measured to evaluate its performance in a direct methanol fuel cell. The on-set degradation temp...
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A novel Nafion®-based nanocomposite membrane was synthesized to be applied as direct methanol fuel cells (DMFCs). Carbon nanotubes (CNTs) were coated with a layer of silica and then reacted by chlorosulfonic acid to produce sulfonate-functionalized silicon dioxide coated carbon nanotubes (CNT@SiO2-SO3H). The functionalized CNTs were then introduced to Nafion®, and subsequently, methanol permeab...
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Sulfonated poly (ether ether ketone) (SPEEK) with a low degree of sulfonation (DS = 40%) was prepared for proton exchange membrane fuel cells (PEMFC). Poly (ether ether ketone) (PEEK) was sulfonated in concentrated H2SO4 under N2 atmosphere and characterized by the hydrogen nuclear magnetic resonance (H-NMR) technique. After preparation of the SPEEK polymer, the obtained polymer was dissolved i...
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Morphology and size of platinum nanoparticles are a crucial factor in improving their catalytic activity and stability. Here, we firstly report the synthesis of high loading Pt nanoparticles on polydopamine reduced Graphene. The loading concentration of Pt (nanoparticles) NPs on Graphene can be adjusted in the range of 60-70%.With the insertion of polydopamine between Graphene oxide sheets, sta...
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